Scalable Synthesis of Multivalent Macromonomers for ROMP
نویسندگان
چکیده
منابع مشابه
ROMP from ROMP: A New Approach to Graft Copolymer Synthesis.
A new strategy is presented for the synthesis of graft copolymers using only the ring-opening metathesis polymerization (ROMP). From a ROMP-derived main chain, pendant maleimide functional groups are converted into norbornene moieties via a Diels-Alder reaction with cyclopentadiene. The norbornene groups serve as sites of initiation, and subsequent ROMP from the main chain yields graft copolyme...
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Ileana Dragutan 1,‡, Valerian Dragutan 1,*,‡, Petru Filip 1,‡, Bogdan C. Simionescu 2,*,‡ and Albert Demonceau 3,‡ 1 Institute of Organic Chemistry, Romanian Academy, 202B Spl. Independentei, P. O. Box 35-108, Bucharest 060023, Romania; [email protected] (I.D.); [email protected] (P.F.) 2 Petru Poni Institute of Macromolecular Chemistry, Romanian Academy, Iasi 700487, Romania; bcsimion@icm...
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Dendronized macromonomers for three-dimensional data storage.
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متن کاملSynthesis of cis,syndiotactic ROMP polymers containing alternating enantiomers.
Ring-opening metathesis polymerization (ROMP) of rac-endo,exo-5,6-dicarbomethoxynorbornene (inter alia) yields a cis,syndio,alt-polymer, one in which the sequential units in the cis,syndiotactic polymer consist of alternating enantiomers. Cis selectivity arises through addition of the monomer to produce an all-cis-metallacyclobutane intermediate, while syndioselectivity and alternating enantiom...
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ژورنال
عنوان ژورنال: ACS Macro Letters
سال: 2018
ISSN: 2161-1653,2161-1653
DOI: 10.1021/acsmacrolett.8b00201